The The use of activated charcoal from corn cobs as adsorbent of heavy metals from groundwater
DOI:
https://doi.org/10.18011/bioeng.2023.v17.1191Keywords:
Activated charcoal, Corn cobs, Heavy metal, GroundwaterAbstract
Iron (Fe) and manganese (Mn) are heavy metals which are found in high concentration in highly weathered soils, especially in the tropics, resulting in high content of them in groundwater. These metals cause a distinctive odor, reddish brown, yellowish color, and high sediment. This condition could cause health problems when it is used as a source of drinking water. This study was aimed to evaluate the efficiency of activated carbon from corn cobs in reducing the concentrations of Fe and Mn from groundwater adsorption. The adsorption process was performed by applying activated carbon with varying doses of 0.1 g, 0.2 g, 0.3 g, 0.4 g, 0.5 g, 1 g, 1.5 g and 2 g into 100 ml groundwater. Variations of pH were pH 2, pH 3, pH 4, pH 5, pH 6, pH 7 and pH 8, and variations in contact time of 10, 30, 45, 60, 90 and 120 minutes. The results showed that the optimum doses to reduce Fe and Mn concentration from groundwater were 1 g and 0.5 g with the adsorption efficiency of 70.14% and 41.60% respectively. The optimum pH for both Fe and Mn was pH 4 with an adsorption efficiency of 75.44% and 56.52% respectively, while the optimum contact times were 60 and 30 minutes with an adsorption efficiency of 75.44 dan 59.29% respectively.
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Abdolali, A., Ngo, H. H., Guo, W. S., Zhou, J. L., Du., Wei, Q., Wang, X. C., and Nguyen, P. D. (2015). Characterization of a multi-metal binding biosorbent: Chemical modification and desorption studies. Bioresour.Technol., 193, 477–487. DOI: https://doi.org/10.1016/j.biortech.2015.06.123
Bagheri, B., Abedi, J. (2011). Adsorption of methane on corn cobs based activated carbon. Chemical Engineering Research and Design, 89(10), 2038-2043. DOI: https://doi.org/10.1016/j.cherd.2011.02.002
Bhatnagar, A., Hogland, W., Marques, M., Sillanpaa, M. 2013. An overview of the modification methods of activated carbon for its water treatment applications. Chemical Engineering Journal, 219, 499–511. DOI: https://doi.org/10.1016/j.cej.2012.12.038
Boudrahem, F., Aissani-Benissad, Ai¨t-Amar, H. (2009). Batch sorption dynamics and equilibrium for the removal of lead ions from aqueous phase using activated carbon developed from coffee residue activated with zinc chloride. J. Environ. Manage., 90,3031–3039. DOI: https://doi.org/10.1016/j.jenvman.2009.04.005
Carretero, S., E. Kruse. (2015). Iron and manganese content in groundwater on the northeastern coast of the Buenos Aires Province, Argentina. Environ. Earth Sci., 73, 1983–1995. DOI: https://doi.org/10.1007/s12665-014-3546-5
Demiral, H., Güngor, C. (2016). Adsorption of copper (II) from aqueous solutions on activated carbon prepared from grape bagasse. Journal of Cleaner Production 124, 103-113. DOI: https://doi.org/10.1016/j.jclepro.2016.02.084
Effendi, M.I., Cahyono, P., Prasetya, B. 2015. Pengaruh toksisitas besi terhadap pertumbuhan dan hasil biomassa pada tiga klon tanaman nanas. Jurnal Tanah dan Sumberdaya Lahan, 2(2), 179-189.
Feng, N.C., Guo, X.Y. (2012). Characterization of adsorptive capacity and mechanisms on adsorption of copper, lead and zinc by modified orange peel. Trans. Nonferrous Met. Soc. China (English Ed.) 22, 1224–1231. DOI: https://doi.org/10.1016/S1003-6326(11)61309-5
Fu, F., Wang, Q. (2011). Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management, 92,407-418. DOI: https://doi.org/10.1016/j.jenvman.2010.11.011
García-Mendieta, A., Solache-Ríos, M., Olguín, M.T. (2009). Evaluation of the sorption properties of a Mexican clinoptilolite-rich tuff for iron, manganese and iron–manganese systems. Microporous and Mesoporous Materials, 118, 489–495. DOI: https://doi.org/10.1016/j.micromeso.2008.09.028
Herviyanti, Prasetyo, T.B., Ahmad, F., Saidi, A. (2012). Humic acid and water management to decrease ferro (Fe2+) solution and increase productivity of established new rice field. J Trop Soils, 17, (1), 9-17. DOI: https://doi.org/10.5400/jts.2012.17.1.9
Hua, M., Zhang, S., Pan, B., Zhang, W., Lv, L, Zhang, Q. (2012). Heavy metal removal from water/wastewater by nanosized metal oxides: A review. Journal of Hazardous Materials, 211, 317– 331. DOI: https://doi.org/10.1016/j.jhazmat.2011.10.016
Huang J., Yuan, F., Zeng, G., Li, X., Gu, Y., Shi, L., Liu, W., Shi, Y. (2017). Influence of pH on heavy metal speciation and removal from wastewater using micellar-enhanced ultrafiltration, Chemosphere, 173, 199–206. DOI: https://doi.org/10.1016/j.chemosphere.2016.12.137
Immamuglu M., Tekir, O. (2008). Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husk. Desalination, 228, 108-113. DOI: https://doi.org/10.1016/j.desal.2007.08.011
Inglezakisa, V.J., Doulab, M.K., Aggelatou, V., Zorpas, A.A. (2020). Removal of iron and manganese from underground water by use of natural minerals in batch mode treatment. Desalin. Water Treat., 18, 341–346. DOI: https://doi.org/10.5004/dwt.2010.1102
Kadir, A.A., Abdulah, M.M. A. B., Sandu, A.V., Noor, N. M., Latif, A.L.A., Hussin, K. (2014). Usage of palm shell activated carbon to treat landfill leachate. International Journal Conservation Science, 5(1), 117-126.
Kusumaningtyas, A.S., Cahyono, P., Sudarto, Suntari, S. (2015). Pengaruh tinggi muka air tanah terhadap pH, Eh, Fe, Aldd, Mn dan P terlarut pada tanaman nanas klon GP3 di Ultisol. Jurnal Tanah dan Sumberdaya Lahan. 2(1), 103-109.
Lasheen, M.R. Ammar, N.S., Ibrahim, H.S. (2012). Adsorption/desorption of Cd(II), Cu(II) and Pb(II) using chemically modified orange peel: Equilibrium and kinetic studies. Solid State Sci., 14, 202–210. DOI: https://doi.org/10.1016/j.solidstatesciences.2011.11.029
Liu. H., Qing, B., Xiushen, Y., Li, Q., Lee, K., Wu,Z. (2009). Boron Adsorption by composite magnetic particles. Journal Chemical Engineering. 151:235-240. DOI: https://doi.org/10.1016/j.cej.2009.03.001
Nursyamsi, D., Suryadi, M.E. (2000). Effect of intermiten drainage and fertilization on pH, Eh, Fe and Mn in Ultisols of Bandar Abung (Lampung and Tapin (Kalsel). Jurnal Ilmu Tanah dan Lingkungan, 3(2), 8-17. DOI: https://doi.org/10.29244/jitl.3.2.8-17
Rusydi, A.F., Onodera, S.I., · Saito, M., ·Ioka, S., Maria, R., Ridwansyah, I., Delinom, R.M., (2021). Vulnerability of groundwater to iron and manganese contamination in the coastal alluvial plain of a developing Indonesian city. SN Applied Sciences, 3, 399 | https://doi.org/10.1007/s42452-021-04385-y DOI: https://doi.org/10.1007/s42452-021-04385-y
Saha, B.C., (2003). Hemicellulose bioconversion. J. Ind. Microbiol. Biotechnol., 30, 279–291. DOI: https://doi.org/10.1007/s10295-003-0049-x
Shamshuddin, J., Daud, N.W. (2011). Classification and management of highly weathered soils in Malaysia for production of plantation crops. In Principles, Application and Assessment in Soil Science. Gungor, B.E.O. (Eds). Intech. Croatia, pp. 75–86. DOI: https://doi.org/10.5772/29490
Srivastava, V.C. Mall, I.D., Mishra, I.M. (2008). Optimization of parameters for adsorption of metal ions onto rice husk ash using Taguchi’s experimental design methodology. Chemical Engineering Journal,140,136–144. DOI: https://doi.org/10.1016/j.cej.2007.09.030
Sych, N. V., Trofymenko, S.I., Poddubnaya, O.I., Tsyba, M. M., Sapsay, V. I., Klymchuk, D. O., Puziy, A.M. (2012). Porous structure and surface chemistry of phosphoric acid activated carbon from corncob. Applied Surface Science, 261, 75–82. DOI: https://doi.org/10.1016/j.apsusc.2012.07.084
Tchounwou, P.T. Yedjou, C. G., Patlolla, A. K., D. J Sutton. (2012). Heavy Metals Toxicity and the Environment. Exp Suppl.,101, 133–164. doi: 10.1007/978-3-7643-8340-4_6 DOI: https://doi.org/10.1007/978-3-7643-8340-4_6
Tian, X., Dai, L., Wang, Y., Zeng, Z., Zhang, S., Jiang, L., Ruan, R. (2020). Influence of torrefaction pretreatment on corncobs: A study on fundamental characteristics, thermal behavior, and kinetic. Bioresource Technology, 297, 122490. DOI: https://doi.org/10.1016/j.biortech.2019.122490
Ucer, A., Uyanik, A., Aygun, S.F. (2006). Adsorption of Cu(II), Cd(II), Zn(II), Mn(II) and Fe(III) ions by tannic acid immobilised activated carbon. Separation and Purification Technology, 47,113–118. DOI: https://doi.org/10.1016/j.seppur.2005.06.012
Ullah, M., Nazir, R., Khan, M., Khan, W. Shah, M., Afridi, S.G., Zada, A. (2020). The effective removal of heavy metals from water by activated carbon adsorbents of Albizia lebbeck and Melia azedarach seed shells. Soil and Water Research, 15, (1) 30–37. https://doi.org/10.17221/212/2018-SWR DOI: https://doi.org/10.17221/212/2018-SWR
Weng, H.X., Qin, Y.C. Chen, X.H. (2007). Elevated iron and manganese concentrations in groundwater derived from the Holocene transgression in the Hang-Jia-Hu Plain, China. Hydrogeol. J. 15, 715–726. https://doi.org/10.1007/s10040-006-0119-z DOI: https://doi.org/10.1007/s10040-006-0119-z
Zhang, X., Hao, Y., Wang, X., Chen, Z. (2017). Rapid removal of zinc(ii) from aqueous solutions using a mesoporous activated carbon prepared from agriculturalwaste. Materials, 10 (9): 1002, doi:10.3390/ma10091002 DOI: https://doi.org/10.3390/ma10091002
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