OBTENÇÃO E CARACTERIZAÇÃO DO BIODIESEL DE CANOLA PELAS ROTAS METÍLICA E ETÍLICA

Autores

  • A.C.F. BATISTA
  • A.T. VIEIRA
  • H.S. RODRIGUES
  • T.A. SILVA
  • R.M.N. ASSUNÇÃO
  • M.A. BELUOMINI
  • H.P. REZENDE
  • M.G. HERNANDEZ-TERRONES

DOI:

https://doi.org/10.18011/bioeng2014v8n4p289-298

Palavras-chave:

óleo de canola, biocombustível

Resumo

Atualmente as reservas de combustíveis fósseis têm diminuído, acarretando um aumento de preço dos derivados do petróleo. Desta forma o biodiesel surge como uma alternativa, sendo o óleo de canola uma opção para esse biocombustível, o qual possui de 40 a 46% de óleo no grão, e que é de excelente qualidade pela composição em ácidos graxos e já usado na Europa para produção de biodiesel. Este trabalho apresenta propriedades físico-químicas do biodiesel de canola nas rotas metílica e etílica através do processo de transesterificação e os resultados encontram-se dentro das normas estabelecidas pela Agência Nacional de Petróleo, Gás Natural e Biocombustíveis (ANP).

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Referências

BP Statistical Review of World Energy. (2012). Retrieved from http://www.bp.com/assets/bp_internet/globalbp/globalbp_uk_english/reports_and_publications/statistical_energy_review_2011/STAGING/local_assets/pdf/statistical_review_of_world_energy_full_report_2012.pdf.

T. A. Silva, A. C. F. Batista, and A. T. Vieira, "A brief discussion of general aspects of Biodiesel Production", Brazilian Geographical Journal: Geosciences and Humanities research medium, vol. 3, no. 1, pp. 80–89, 2012.

A. P. Vyas, J. L. Verma, and N. Subrahmanyam, "A review on FAME production processes", Fuel, vol. 89, no. 1, pp. 1–9, 2010.

S. A. Montzka, E. J. Dlugokencky, and J. H. Butler, "Non-CO2 greenhouse gases and climate change", Nature, vol. 476, pp. 43–50, 2011.

D. J. Hofmann, J. H. Butler, E. J. Dlugokencky, J. W. Elkins, K. Masarie, S. A. Montzka, and P. Tans, "The role of carbon dioxide in climate forcing from 1979 - 2004: Introduction of the Annual Greenhouse Gas Index", Tellus B, vol. 58, pp. 614–619, 2008.

L. L. N. Guarieiro, P. C. Vasconcellos, and M. C. Solci, "Air Pollutants from the Burning of Fossil Fuels and Biofuels: A Brief Review", Revista Virtual de Química, vol. 3, no. 5, pp. 434–445, 2011.

Petróleo – Agência Nacional de Energia Elétrica.< http://www.aneel.gov.br/aplicacoes/atlas/pdf/07-Petroleo(2).pdf> [Acessed June 2012].

W. Körbitz, "Biodiesel production in Europe and North America, an encouraging prospect", Renewable Energy, vol. 16, no. 10, pp. 1078–1083, 1999.

F. C. C. Oliveira, P. A. Z. Suarez, and W. L. P. Santos, "Biodiesel: Possibilidades e Desafios", Química Nova na Escola, vol. 28, pp. 3–8, 2007.

D. Y. C. Leung, X. Wu, and M. K. H. Leung, "A review on biodiesel production using catalyzed transesterification", Applied Energy, vol. 87, no. 4, pp. 1083–1095, 2010.

B. L. Salvi and N. L. Panwar, "Biodiesel resources and production technologies – A review", Renewable and Sustainable Energy Reviews, vol. 16, no. 6, pp. 3680–3689, 2012.

M. C. G. Albuquerque, Y. L. Machado, A. E. B. Torres, D. C. S. Azevedo, C. L. Cavalcante Jr., L. R. Firmiano, and E. J. S. Parente Jr., "Properties of biodiesel oils formulated using different biomass sources and their blends", Renewable Energy, vol. 34, no. 3, pp. 857–859, 2009.

R. Rinaldi, C. Garcia, L. L. Marciniuk, A. V. Rossi, and U. Schuchardt, "Synthesis of biodiesel: a contextualized experiment proposal for the general chemistry laboratory", Química Nova, vol. 30, no. 5, 1374–1380, 2007.

N. L. Silva, M. R. W. Maciel, C. B. Batistella, and R. M. Filho, Optimization of biodiesel production from castor oil", Applied Biochemistry and Biotechnology, vol. 130, no. 1, pp. 405–414, 2006.

Y. Zhang, M. A. Dubé, D. D. McLean, and M. Kates, "Biodiesel production from waste cooking oil: 1. Process design and technological assessment", Bioresource Technology, vol. 89, no. 1, pp. 1–16, 2003.

A. C. Pinto, L. L. N. Guarieiro, M. J. C. Rezende, N. M. Ribeiro, E. A. Torres, W. A. Lopes, P. A. P. Pereira, and J. B. de Andrade, "Biodiesel: An Overview", Journal of the Brazilian Chemical Society, vol. 16, no. 6, pp. 1313–1330, 2005.

E. M. Shahid and Y. Jamal, "Production of biodiesel: A technical review", Renewable and Sustainable Energy Reviews, vol. 15, no. 9, pp. 4732–4745, 2011.

A. E. Atabani, A. S. Silitonga, I. A. Badruddin, T. M. I. Mahlia, H. H. Masjuki, and S. Mekhilef, "A comprehensive review on biodiesel as an alternative energy resource and its characteristics", Renewable and Sustainable Energy Reviews, vol. 16, no. 4, pp. 2070–2093, 2012.

A. D' Cruz, M. G. Kulkarni, L. C. Meher, and A. K. Dalai, "Synthesis of biodiesel from canola oil using heterogeneous base catalyst", Journal of American Oil Chemist's Society, vol. 84, no. 10, pp. 937–943, 2007.

F. Ataya, M. A. Dubé, and M. Ternan, "Acid-catalyzed transesterification of canola oil to biodiesel under single- and two-phase reaction conditions", Energy & Fuels, vol. 21, no. 4, pp. 2450–2459, 2007.

N. Dizge and B. Keskinler, "Enzymatic production of biodiesel from canola oil using immobilized lipase", Biomass and Bioenergy, vol. 32, no. 12, pp. 1274–1278, 2008.

D. M. Haagenson, R. L. Brudvik, H. Lin, and D. P. Wiesenborn, "Implementing an In Situ Alkaline Transesterification Method for Canola Biodiesel Quality Screening", Journal of American Oil Chemist's Society, vol. 87, no. 11, pp. 1351–1358, 2010.

S. B. Lee, J. D. Lee, and I. K. Hong, "Ultrasonic energy effect on vegetable oil based biodiesel synthetic process", Journal of Industrial and Engineering Chemistry, vol. 17, no. 1, pp. 138–143, 2011.

S. Lee, D. Posarac, and N. Ellis, "An experimental investigation of biodiesel synthesis from waste canola oil using supercritical methanol", Fuel, vol. 91, no. 1, 229–237, 2012.

N. Jorge, B. B. P. Soares, V. M. Lunardi, and C. R. Malacrida, "Physico-chemical alterations of sunflower, corn and soybean oils in deep fat frying", Química Nova, vol. 28, no. 6, pp. 947–951, 2005.

U. Schuchardta, R. Serchelia, and R.M. Vargas, "Transesterification of Vegetable Oils: a Review", Journal of the Brazilian Chemical Society, vol. 9, no. 1, pp. 199–210, 1998.

D. M. Fernandes, D. S. Serqueira, F. M. Portela, R. M. N. Assunção, R. A. A. Munoz, M. G. H. Terrones MGH, "Preparation and characterization of methylic and ethylic biodiesel from cottonseed oil and effect of tert-butylhydroquinone on its oxidative stability", Fuel, vol. 97, pp. 658–661, 2012.

L. C. Meher, D. V. Sagar, and S. N. Naik, "Technical aspects of biodiesel production by transesterification – a review", Renewable and Sustainable Energy Reviews, 10 (3), 248-268 (2006).

F. Ma and M. A. Hanna. "Biodiesel production: a review". Bioresource Technology, 70 (1), 1-15 (1999).

M. Balat and H. Balat, "A critical review of bio-diesel as a vehicular fuel", Energy Conversion and Management, 49 (10), 2727-2741 (2008).

B. Freedman, E. H. Pryde, and T. L. Mounts, "Variables Affecting the Yields of Fatty Esters from Transesterified Vegetable Oils", Journal of the American Oil Chemical Society, 61 (10), 1638-1643 (1984).

Y. H. Chen, J. H. Chen, C. Y. Chang, and C. C. Chang, "Biodiesel production from tung (Vernicia montana) oil and its blending properties in different fatty acid compositions", Bioresource Technology, 101 (24), 9521-9526 (2010).

O. J. Alamu, M. A. Waheed, and S. O. Jekayinfa, "Effect of ethanol–palm kernel oil ratio on alkali-catalyzed biodiesel yield", Fuel, 87 (8), 1529-1533 (2008).

K. Ramezani, S. Rowshanzamir, and M. H. Eikani, "Castor oil transesterification reaction: A kinetic study and optimization of parameters", Energy, 35 (10), 4142-4148 (2010).

M. F. Oliveira, A. T. Vieira, A. C. F. Batista, H. S. Rodrigues, and N. R. Stradiotto, "A simple and fast method for the production and characterization of methylic and ethylic biodiesels from tucum oil via an alkaline route", Journal of Biomedicine and Biotechnology, 2011, 1–4, 2

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Publicado

16-12-2014

Como Citar

BATISTA, A., VIEIRA, A., RODRIGUES, H., SILVA, T., ASSUNÇÃO, R., BELUOMINI, M., REZENDE, H., & HERNANDEZ-TERRONES, M. (2014). OBTENÇÃO E CARACTERIZAÇÃO DO BIODIESEL DE CANOLA PELAS ROTAS METÍLICA E ETÍLICA. Revista Brasileira De Engenharia De Biossistemas, 8(4), 289–298. https://doi.org/10.18011/bioeng2014v8n4p289-298

Edição

Seção

Regular Section