REMEDIATION OF TEXTILE DYES MIXTURES USING TIO2/VIS PHOTOCATALYSIS AND FENTON FE2+/H2O2
DOI:
https://doi.org/10.18011/bioeng2015v9n4p328-338Keywords:
treatment technology, textile industry, remediationAbstract
This study aimed to use the following treatment technology: TiO2 photocatalysis and Fenton reaction for the remediation of mixture of textile dyes. For the photocatalytic treatment it was obtained a reduction in color of 80% and Chemical Oxygen Demand of 60% using for this 600 mg L-1 of TiO2, 1500 mL min-1 recirculation flow, temperature 40 oC/45 oC and pH = 6.3 for 60 minutes of treatment. By Fenton reaction it was reached color reduction at 95% and Chemical Oxygen Demand reduction at 75% employing 60 mg L-1 H2O2, 50 mg L-1 de Fe2+ and pH = 4.0 for 62 minutes of treatment.
Downloads
References
ALMEIDA, M.F. Avaliação do processo de adsorção-fotodegradação com esferas de TiO2- quitosana para o tratamento de efluentes de indústria textile. (Evaluation of the photodegradation-adsorption process with TiO2 spheres-chitosan for treating textile industry wastewater) 114 pg. Master's Thesis in Agrochemistry – Viçosa Federal University, 2011.
AMERICAN PUBLIC HEALTH ASSOCIATION-APHA. Standard Methods for the Water and Wastewater. 20 ed. New York: APHA, 1998.
BORBA, F. H.; SOTTORIVA, P. R. S.; MÓDENES, A. N.; Tratamento do efluente madeireiro por processo foto-Fenton. (Treatment of timber industry wastewater by photo-Fenton process.) Estudos Tecnológicos, v.4 (1):12-20, 2008.
BIANCO, B.; MICHELIS, I.; VEGLIÓ, F. Fenton treatment of complex industrial wastewater: Optimization of process conditions by surface response method. Journal Materials Hazardous, v.186:1733-1738, 2011.
BRITO, N.N.; ARCHANJO, G.B.; PELEGRIN, R.; PATERNIANI, J.E.S.; Otimização do processo fotocatalítico heterogêneo para o tratamento de percolado de aterro sanitário. (Optimization of heterogeneous photocatalytic process for the treatment of landfill leachate) Eclética Química, v. 36 (3):1-7, 2011.
CAMPOS, V.M; BRITO, N. N.; Photochemical Treatment with H2O2/UV Applied to the Remediation of Dispersive Textile Dye. Oxidation Communication, v. 37 (2): 583-595, 2014.
CLAUSEN, D.N.; TAKASHIMA K.; Efeitos dos parâmetros operacionais na fotodegradação do azo corante direct red 23 na interface dióxido de titânio/água. (Effects of operational parameters in the photo degradation of Direct Red 23 azo dye in the titanium dioxide / water interface.) Química Nova, v. 30 (8): 1896-1899, 2007.
CONSELHO NACIONAL DO MEIO AMBIENTE (CONAMA). Resolução 430 de 13/05/2011. Dispõe as condições e padrões de lançamento de efluentes completa e altera a resolução n.357/2005 do conselho nacional do meio ambiente CONAMA.( Resolution 430 of 13/05/2011. Conditions and discharge standards for wastewater. It changes the resolution n.357 / 2005 of the National Council of Environment CONAMA.)
DAMODAR, R.A.; YOU, S.J.; Performance of an integrated membrane photocatalytic reactor for removal of reactive Black 5. Separation and Purification Technology, v.71(1):44-49, 2010.
DA SILVA, W.L.; LANSARIN, M.A.; MORO, C.C.; Síntese, caracterização e atividade fotocatalítica de catalisadores nanoestruturados de TiO2 Dopados com metais. (Synthesis, characterization and photocatalytic activity of nanostructured catalysts of TiO2 doped with metals.) Química Nova, v. 36 (3):382-386, 2013.
DIAS, Z. M. M. S. Degradação do Benzo(a)Pireno em Matrizes Aquosas por Oxidação Química com Reagente de Fenton.(Degradation of benzo(a)pyrene in aqueous matrices by Chemical Oxidation with Fenton Reagent)146f. Master's Thesis in. Sanitation Engineering and Construction - University of Porto-Department of Chemical Engineering, Porto, 2008.
FERREIRA, I.V.L.; DANIEL, L.A. Fotocatálise heterogênea com TiO2 aplicada ao tratamento de esgoto sanitário secundário. Revista Engenharia Sanitária e Ambiental, v.9: (4), 335-342, 2004.
KARTHIKEYAN, S.; TITUS, A.; GNANAMANI, A.; MANDAL, A.B.; SEKARAN, M.G.; Treatment of textile wastewater by homogeneous and heterogeneous Fenton oxidation processes. Desalination, v.281: 438-445, 2011.
LIMA, G.G.C.; LIMA, C.A.P.; VIEIRA, F.F.; SILVA, E.M.; Estudo comparativo da aplicação de nanopartículas de TiO2 e ZnO na descoloração fotocatalítica de uma solução de corante empregando radiação UV artificial. (Comparative study of the application of TiO2 nanoparticles and ZnO in the photocatalytic discoloration of a dye solution using artificial UV radiation) Revista Eletrônica de Materiais e Processos, v. 9 (1): 22-27, 2014.
MA, X.J.; XIA, H.L.; Treatment of water-based printing ink wastewater by Fenton process combined with coagulation. Journal Hazardous Materials, v. 162 (1): 386-390, 2009.
MATTOS, I.L.; SHIRAISHI, K.A.; BRAZ, A.D.; FERNANDES, J.R.; Peróxido de Hidrogênio: Importância e Determinação, (Hydrogen Peroxide: Importance and determination) Química Nova, v. 26 (3): 373-380, 2003.
MORAIS, W.O; BRITO, N. N.; Tratamento via reação de Fenton de efluente simulado da linha de produção de filtro solar.(Treatment via Fenton reaction of simulated wastewater of sunscreen production line.) In: 11 Congresso de Ensino Pesquisa e Extensão, 2014, Goiânia. 11 Congresso de Ensino Pesquisa e Extensão- Conpeex. Goiânia: UFG, v.11: 1-4, 2014.
OLIVEIRA, M.C.; NOGUEIRA, R.F.P.; NETO, J.A.G.; JARDIM, W.F.; ROHWEDDER, J.J.R.; Sistema de injeção em fluxo espectrofotométrico para monitorar peróxido de hidrogênio em processo de fotodegradação por reação fotofenton.(Injection system for spectrophotometric flow to monitor hydrogen peroxide in photo degradation process by photo Fenton reaction.) Química Nova, v. 24 (2):188-190, 2001.
RAMÓN-SANCHEZ, R.M.; SOARES, A.A.; SEDIYAMA, G.C.; MATOS, A.T.; Potential use of solar radiation to disinfect domestic wastewater in Brazil. Brazilian Journal of Biosystems Engineering Bioeng, v.2 (3): 283-294, 2008.
SOUTSAS, K.; KARAYANNIS, V.; POULIOS, I.; RIGA, A.; NTAMPEGLIOTIS, K.; SPILIOTIS, X.; PAPAPOLYMEROU, G.; Decolorization and degradation of reactive azo dyes via heteregoneous photocatalytic processes. Desalination, v. 250:345-350, 2010.
SOON, A.N.; HAMEED, B.H. Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process. Desalination, v.269:1-16, 2011.
SOUZA, S.J.O.; LOBO, T.M.; SABINO, A.L.O.; OLIVEIRA, S.B.; COSTA, O.S.; Decomposição dos antirretrovirais lamivudina e zidovudina pelo processo fotofenton assistido no efluente de indústria farmoquímica. (Breakdown of antiretroviral drugs lamivudine and zidovudine assisted by photo Fenton process in pharmaceutical chemistry industry wastewater.) Revista Processos Químicos, v. 4 (7): 59-67, 2010.
TEKIN, D.; Photocatalytic degradation of textile dyestuffs using TiO2 nanotubes prepared by sonoelectrochemical method. Applied Surface Science, v. 318: 132-136, 2014.
VILLOTA, N., CAMARERO, L.M., LOMAS, J.M., PEREZ, J. Changes of turbidity during the phenol oxidation by photo-Fenton treatment. Environmental Science Pollution Research, v. 21:12208-12216, 2014.
WU, Y.; ZHOU, S.; YE, X.; ZHAO, R.; CHEN, D. Colloids and surfaces A: Pysicochemical and Engineering Aspects. Colloids and Surface A: Pysicochemistry Engineering Aspects, v. 379:151-156, 2011.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2015 P. M. Andrade, M. A. F. Carvalho, A. S. Miranda, H. R. Marques, S. R. Campos, N. N. Brito Brito
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish in this journal agree to the following terms:
a) Authors retain the copyright and grant the journal the right of first publication, with the work simultaneously licensed under the Creative Commons Attribution License that allows the sharing of the work with recognition of authorship and initial publication in this journal.
b) Authors are authorized to assume additional contracts separately, for non-exclusive distribution of the version of the work published in this journal (eg, publish in an institutional repository or as a book chapter), with recognition of authorship and initial publication in this journal.
